25 most expensive cards in Pokmon TCG Prismatic Evolutions Pokemon Vivid Voltage Charizard #25 185 Non Holofoil Rare Ascended Heroes . the 9 most expensive pokemon cards. Gengar SAR pokemon card is over $1,000. Is this the best pokemon pack value wise to open if you can find it MSRP? Amazon.com: Pokemon 5 Full Art Trainer Card Lot X1 Secret Rare, X4 Full Art Etched Cards No Duplicates : Toys & Games Most Expensive Pokemon Vivid Voltage Pokemon Cards